Frustrated Lewis Pairs Database

FLPID: 0BP16032

FLP

LA-LB distance (d/Å):2.008

hydride affinity (ΔG°H/eV) :-4.01

proton affinity (ΔG°H+/eV) :8.62

HOMO-LUMO Gap (ΔEg/eV):5.9

hardness of LA (η/eV):0.109

softness of LA (S/eV):4.593

CM5 charge of LA (e):-0.241

CM5 charge of LB (e):0.150

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):3.476

Electronic energy of H2 binding, ΔE = 14.8 kcal/mol

Ethalpy of H2 binding, ΔH° = 18.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 24.1 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.577

Electronic energy of H2 binding, ΔE = 13.0 kcal/mol

Ethalpy of H2 binding, ΔH° = 13.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 22.2 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):3.680

Electronic energy of H2 binding, ΔE = -3.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -2.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 8.2 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -18.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -16.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -5.2 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -13.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -11.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -0.5 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -0.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -0.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 11.3 kcal/mol

xyz coordinates: Download