Frustrated Lewis Pairs Database

FLPID: 0BP16031

FLP

LA-LB distance (d/Å):2.049

hydride affinity (ΔG°H/eV) :-3.93

proton affinity (ΔG°H+/eV) :9.02

HOMO-LUMO Gap (ΔEg/eV):6.0

hardness of LA (η/eV):0.110

softness of LA (S/eV):4.556

CM5 charge of LA (e):-0.227

CM5 charge of LB (e):0.146

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):3.418

Electronic energy of H2 binding, ΔE = 19.8 kcal/mol

Ethalpy of H2 binding, ΔH° = 23.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 29.0 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.374

Electronic energy of H2 binding, ΔE = 16.6 kcal/mol

Ethalpy of H2 binding, ΔH° = 17.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 27.7 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):3.555

Electronic energy of H2 binding, ΔE = 0.7 kcal/mol

Ethalpy of H2 binding, ΔH° = 2.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 11.9 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = 18.1 kcal/mol

Ethalpy of H2 binding, ΔH° = 19.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 24.1 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -5.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -5.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 3.8 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):3.538

Electronic energy of H2 binding, ΔE = -1.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -0.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 11.0 kcal/mol

xyz coordinates: Download