Frustrated Lewis Pairs Database

FLPID: 0BP15032

FLP

LA-LB distance (d/Å):2.229

hydride affinity (ΔG°H/eV) :-4.73

proton affinity (ΔG°H+/eV) :7.81

HOMO-LUMO Gap (ΔEg/eV):7.1

hardness of LA (η/eV):0.131

softness of LA (S/eV):3.821

CM5 charge of LA (e):-0.178

CM5 charge of LB (e):0.114

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):3.252

Electronic energy of H2 binding, ΔE = -10.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -6.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 1.4 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.134

Electronic energy of H2 binding, ΔE = -5.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -4.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 8.9 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):2.724

Electronic energy of H2 binding, ΔE = -17.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -16.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -5.9 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):3.136

Electronic energy of H2 binding, ΔE = -29.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -25.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -10.8 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):3.422

Electronic energy of H2 binding, ΔE = -28.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -27.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -15.0 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):3.251

Electronic energy of H2 binding, ΔE = -19.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -18.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -6.2 kcal/mol

xyz coordinates: Download