Frustrated Lewis Pairs Database

FLPID: 0BP15031

FLP

LA-LB distance (d/Å): 3.463

hydride affinity (ΔG°H/eV):-4.57

proton affinity (ΔG°H+/eV):7.67

HOMO-LUMO Gap (ΔEg/eV): 4.37

hardness of LA (η/eV):0.080

softness of LA (S/eV):6.220

CM5 charge of LA (e): -0.07

CM5 charge of LB (e): -0.02

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 3.630

Electronic energy of H2 binding, ΔE = -9.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -5.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 7.2 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 3.258

Electronic energy of H2 binding, ΔE = -10.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -9.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 5.9 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 3.334

Electronic energy of H2 binding, ΔE = -24.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -24.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -10.4 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):3.492

Electronic energy of H2 binding, ΔE = -37.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -34.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -16.9 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 3.498

Electronic energy of H2 binding, ΔE = -21.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -20.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -2.4 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 3.069

Electronic energy of H2 binding, ΔE = -19.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -18.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -2.6 kcal/mol

xyz coordinates: Download