Frustrated Lewis Pairs Database

FLPID: 0BP07011

FLP

LA-LB distance (d/Å): 2.217

hydride affinity (ΔG°H/eV):-4.60

proton affinity (ΔG°H+/eV):7.72

HOMO-LUMO Gap (ΔEg/eV): 5.26

hardness of LA (η/eV):0.097

softness of LA (S/eV):5.170

CM5 charge of LA (e): -0.18

CM5 charge of LB (e): 0.11

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 3.193

Electronic energy of H2 binding, ΔE = -5.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -1.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 6.5 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 3.156

Electronic energy of H2 binding, ΔE = -5.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -4.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 8.1 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 3.253

Electronic energy of H2 binding, ΔE = -16.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -16.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -5.4 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):

Electronic energy of H2 binding, ΔE = -33.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -30.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -16.1 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 3.460

Electronic energy of H2 binding, ΔE = -27.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -27.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -16.8 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):3.370

Electronic energy of H2 binding, ΔE = -16.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -15.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -4.7 kcal/mol

xyz coordinates: Download