Frustrated Lewis Pairs Database

FLPID: 0BP12011

FLP

LA-LB distance (d/Å): 2.152

hydride affinity (ΔG°H/eV):-4.42

proton affinity (ΔG°H+/eV):7.73

HOMO-LUMO Gap (ΔEg/eV): 5.62

hardness of LA (η/eV):0.103

softness of LA (S/eV):4.843

CM5 charge of LA (e): -0.20

CM5 charge of LB (e): 0.13

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 3.542

Electronic energy of H2 binding, ΔE = -4.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -0.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 6.9 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 3.225

Electronic energy of H2 binding, ΔE = -9.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -8.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 3.9 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 3.331

Electronic energy of H2 binding, ΔE = -21.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -20.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -11.7 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):3.635

Electronic energy of H2 binding, ΔE = 5.7 kcal/mol

Ethalpy of H2 binding, ΔH° = 6.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 18.0 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 3.438

Electronic energy of H2 binding, ΔE = -15.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -16.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -7.7 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 3.372

Electronic energy of H2 binding, ΔE = -13.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -13.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 0.0 kcal/mol

xyz coordinates: Download