Frustrated Lewis Pairs Database

FLPID: 0BP13011

FLP

LA-LB distance (d/Å): 3.462

hydride affinity (ΔG°H/eV):-4.88

proton affinity (ΔG°H+/eV):7.42

HOMO-LUMO Gap (ΔEg/eV): 3.99

hardness of LA (η/eV):0.073

softness of LA (S/eV):6.823

CM5 charge of LA (e): -0.06

CM5 charge of LB (e): -0.02

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 3.449

Electronic energy of H2 binding, ΔE = -17.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -13.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -3.0 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 3.298

Electronic energy of H2 binding, ΔE = -18.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -17.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -1.6 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 3.539

Electronic energy of H2 binding, ΔE = -31.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -30.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -18.0 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):3.281

Electronic energy of H2 binding, ΔE = -44.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -41.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -24.9 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 3.639

Electronic energy of H2 binding, ΔE = -40.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -39.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -25.5 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 3.499

Electronic energy of H2 binding, ΔE = -29.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -28.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -12.5 kcal/mol

xyz coordinates: Download