Frustrated Lewis Pairs Database

FLPID: 0AP12011

FLP

LA-LB distance (d/Å):3.342

hydride affinity (ΔG°H/eV) :-3.68

proton affinity (ΔG°H+/eV) :7.68

HOMO-LUMO Gap (ΔEg/eV):6.9

hardness of LA (η/eV):0.126

softness of LA (S/eV):3.972

CM5 charge of LA (e):0.320

CM5 charge of LB (e):-0.031

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):3.233

Electronic energy of H2 binding, ΔE = 3.6 kcal/mol

Ethalpy of H2 binding, ΔH° = 6.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 15.9 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.793

Electronic energy of H2 binding, ΔE = -7.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -7.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -0.1 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 3.299

Electronic energy of H2 binding, ΔE = -22.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -20.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -8.0 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):3.377

Electronic energy of H2 binding, ΔE = -20.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -18.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -6.5 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 3.375

Electronic energy of H2 binding, ΔE = -33.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -31.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -16.4kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 3.382

Electronic energy of H2 binding, ΔE = -24.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -22.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -10.4 kcal/mol

xyz coordinates: Download