Frustrated Lewis Pairs Database

FLPID: 0BP07022

FLP

LA-LB distance (d/Å):4.426

hydride affinity (ΔG°H/eV) :

proton affinity (ΔG°H+/eV) :

HOMO-LUMO Gap (ΔEg/eV):8.1

hardness of LA (η/eV):0.148

softness of LA (S/eV):3.377

CM5 charge of LA (e):-0.245

CM5 charge of LB (e):0.183

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):4.541

Electronic energy of H2 binding, ΔE = 53.2 kcal/mol

Ethalpy of H2 binding, ΔH° = 56.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 60.4 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):4.316

Electronic energy of H2 binding, ΔE = 11.9 kcal/mol

Ethalpy of H2 binding, ΔH° = 11.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 18.5 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):4.408

Electronic energy of H2 binding, ΔE = -8.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -6.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 2.2 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):4.379

Electronic energy of H2 binding, ΔE = -6.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -4.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 4.9 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):4.403

Electronic energy of H2 binding, ΔE = -14.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -12.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -1.1 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):4.429

Electronic energy of H2 binding, ΔE = -7.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -6.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 3.4 kcal/mol

xyz coordinates: Download