Frustrated Lewis Pairs Database

FLPID: 0BP13072

FLP

LA-LB distance (d/Å):3.646

hydride affinity (ΔG°H/eV) :-4.79

proton affinity (ΔG°H+/eV) :8.87

HOMO-LUMO Gap (ΔEg/eV):6.2

hardness of LA (η/eV):0.115

softness of LA (S/eV):4.356

CM5 charge of LA (e):-0.075

CM5 charge of LB (e):0.014

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):3.582

Electronic energy of H2 binding, ΔE = 12.5 kcal/mol

Ethalpy of H2 binding, ΔH° = 16.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 26.7 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.923

Electronic energy of H2 binding, ΔE = 3.4 kcal/mol

Ethalpy of H2 binding, ΔH° = 4.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 17.3 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):4.108

Electronic energy of H2 binding, ΔE = -13.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -10.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -0.2 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):3.050

Electronic energy of H2 binding, ΔE = -28.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -25.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -11.0 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):4.291

Electronic energy of H2 binding, ΔE = -9.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -7.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 4.6 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 3.546

Electronic energy of H2 binding, ΔE = -17.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -15.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -2.8 kcal/mol

xyz coordinates: Download