Frustrated Lewis Pairs Database

FLPID: 0BP14024

FLP

LA-LB distance (d/Å):2.035

hydride affinity (ΔG°H/eV) :-4.71

proton affinity (ΔG°H+/eV) :8.71

HOMO-LUMO Gap (ΔEg/eV):7.2

hardness of LA (η/eV):0.133

softness of LA (S/eV):3.757

CM5 charge of LA (e):-0.214

CM5 charge of LB (e):0.145

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 3.108

Electronic energy of H2 binding, ΔE = 0.2 kcal/mol

Ethalpy of H2 binding, ΔH° = 4.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 11.8 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.195

Electronic energy of H2 binding, ΔE = -2.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -1.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 11.6 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 3.421

Electronic energy of H2 binding, ΔE = -0.9 kcal/mol

Ethalpy of H2 binding, ΔH° = 0.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 12.1 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):3.161

Electronic energy of H2 binding, ΔE = -34.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -31.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -16.7 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):3.327

Electronic energy of H2 binding, ΔE = -15.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -15.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -2.9 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):3.362

Electronic energy of H2 binding, ΔE = -11.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -11.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 2.7 kcal/mol

xyz coordinates: Download