Frustrated Lewis Pairs Database

FLPID: 0BP14023

FLP

LA-LB distance (d/Å):2.033

hydride affinity (ΔG°H/eV) :-4.67

proton affinity (ΔG°H+/eV) :8.77

HOMO-LUMO Gap (ΔEg/eV):7.2

hardness of LA (η/eV):0.133

softness of LA (S/eV):3.764

CM5 charge of LA (e):-0.214

CM5 charge of LB (e):0.145

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):3.101

Electronic energy of H2 binding, ΔE = 1.7 kcal/mol

Ethalpy of H2 binding, ΔH° = 5.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 12.9 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.193

Electronic energy of H2 binding, ΔE = 3.5 kcal/mol

Ethalpy of H2 binding, ΔH° = 4.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 17.8 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):3.067

Electronic energy of H2 binding, ΔE = -10.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -8.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 5.2 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):3.426

Electronic energy of H2 binding, ΔE = 33.5 kcal/mol

Ethalpy of H2 binding, ΔH° = 34.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 49.5 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):3.261

Electronic energy of H2 binding, ΔE = -12.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -12.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 1.7 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):3.407

Electronic energy of H2 binding, ΔE = -9.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -8.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 4.2 kcal/mol

xyz coordinates: Download