Frustrated Lewis Pairs Database

FLPID: 0BP14022

FLP

LA-LB distance (d/Å):2.09

hydride affinity (ΔG°H/eV) :-4.98

proton affinity (ΔG°H+/eV) :8.23

HOMO-LUMO Gap (ΔEg/eV): 7.2

hardness of LA (η/eV):0.132

softness of LA (S/eV):3.781

CM5 charge of LA (e): -0.201

CM5 charge of LB (e): 0.146

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):3.036

Electronic energy of H2 binding, ΔE = -9.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -5.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -0.3 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.105

Electronic energy of H2 binding, ΔE = -3.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -2.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 10.0 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):3.214

Electronic energy of H2 binding, ΔE = -21.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -20.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -9.5 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):3.214

Electronic energy of H2 binding, ΔE = -30.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -27.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -15.7 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):3.551

Electronic energy of H2 binding, ΔE = -2.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -2.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 8.8 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):3.406

Electronic energy of H2 binding, ΔE = -11.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -11.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -1.1 kcal/mol

xyz coordinates: Download