Frustrated Lewis Pairs Database

FLPID: 0BP14021

FLP

LA-LB distance (d/Å): 3.445

hydride affinity (ΔG°H/eV) :-5.25

proton affinity (ΔG°H+/eV) :7.98

HOMO-LUMO Gap (ΔEg/eV):5.0

hardness of LA (η/eV):0.093

softness of LA (S/eV):5.401

CM5 charge of LA (e): -0.075

CM5 charge of LB (e): 0.018

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 3.038

Electronic energy of H2 binding, ΔE = -19.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -15.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -5.1 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):2.163

Electronic energy of H2 binding, ΔE = -16.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -14.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 2.9 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):3.242

Electronic energy of H2 binding, ΔE = -19.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -17.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -3.7 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):3.124

Electronic energy of H2 binding, ΔE = -43.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -39.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -22.6 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):3.250

Electronic energy of H2 binding, ΔE = -19.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -18.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -3.5 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):3.416

Electronic energy of H2 binding, ΔE = -19.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -18.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -5.4 kcal/mol

xyz coordinates: Download