Frustrated Lewis Pairs Database

FLPID: 0BN13021

FLP

LA-LB distance (d/Å):3.606

hydride affinity (ΔG°H/eV) :-4.85

proton affinity (ΔG°H+/eV) :7.87

HOMO-LUMO Gap (ΔEg/eV):5.8

hardness of LA (η/eV):0.107

softness of LA (S/eV):4.687

CM5 charge of LA (e):-0.057

CM5 charge of LB (e):-0.360

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 3.721

Electronic energy of H2 binding, ΔE = -16.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -9.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 2.5 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.580

Electronic energy of H2 binding, ΔE = -2.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -1.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 6.9 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):3.606

Electronic energy of H2 binding, ΔE = -10.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -8.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 6.3 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):3.704

Electronic energy of H2 binding, ΔE = -0.1 kcal/mol

Ethalpy of H2 binding, ΔH° = 2.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 17.0 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 3.572

Electronic energy of H2 binding, ΔE = -2.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -1.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 13.8 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):3.590

Electronic energy of H2 binding, ΔE = -13.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -10.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 4.9 kcal/mol

xyz coordinates: Download