Frustrated Lewis Pairs Database

FLPID: 0BP12021

FLP

LA-LB distance (d/Å):7.449

hydride affinity (ΔG°H/eV) :-4.91

proton affinity (ΔG°H+/eV) :7.53

HOMO-LUMO Gap (ΔEg/eV):5.7

hardness of LA (η/eV):0.104

softness of LA (S/eV):4.788

CM5 charge of LA (e):-0.064

CM5 charge of LB (e):-0.041

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 7.466

Electronic energy of H2 binding, ΔE = 1.3 kcal/mol

Ethalpy of H2 binding, ΔH° = 5.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 15.5 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):7.496

Electronic energy of H2 binding, ΔE = -4.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -3.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 3.0 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):7.437

Electronic energy of H2 binding, ΔE = -6.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -5.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° =1.8 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å): 7.443

Electronic energy of H2 binding, ΔE = -4.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -3.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 4.6 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 7.431

Electronic energy of H2 binding, ΔE = -14.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -13.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -5.0 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 7.432

Electronic energy of H2 binding, ΔE = -7.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -6.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 3.4 kcal/mol

xyz coordinates: Download