Frustrated Lewis Pairs Database

FLPID: 0BN15036

FLP

LA-LB distance (d/Å):7.580

hydride affinity (ΔG°H/eV) :-4.83

proton affinity (ΔG°H+/eV) :7.96

HOMO-LUMO Gap (ΔEg/eV):6.3

hardness of LA (η/eV):0.116

softness of LA (S/eV):4.321

CM5 charge of LA (e):-0.055

CM5 charge of LB (e):-0.340

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):5.672

Electronic energy of H2 binding, ΔE = 2.1 kcal/mol

Ethalpy of H2 binding, ΔH° = 8.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 20.2 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):7.584

Electronic energy of H2 binding, ΔE = -3.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -2.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 5.4 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):7.583

Electronic energy of H2 binding, ΔE = -8.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -7.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 2.1 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):7.499

Electronic energy of H2 binding, ΔE = -5.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -3.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 5.5 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):7.582

Electronic energy of H2 binding, ΔE = -17.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -15.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -4.5 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):7.566

Electronic energy of H2 binding, ΔE = -17.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -15.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -1.3 kcal/mol

xyz coordinates: Download