Frustrated Lewis Pairs Database

FLPID: 0BN15035

FLP

LA-LB distance (d/Å):1.654

hydride affinity (ΔG°H/eV) :-4.37

proton affinity (ΔG°H+/eV) :8.36

HOMO-LUMO Gap (ΔEg/eV):6.8

hardness of LA (η/eV):0.124

softness of LA (S/eV):4.023

CM5 charge of LA (e):-0.163

CM5 charge of LB (e):-0.198

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):3.485

Electronic energy of H2 binding, ΔE = 7.0 kcal/mol

Ethalpy of H2 binding, ΔH° = 11.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 17.1 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.762

Electronic energy of H2 binding, ΔE = 11.0 kcal/mol

Ethalpy of H2 binding, ΔH° = 12.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 22.4 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):3.519

Electronic energy of H2 binding, ΔE = -12.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -12.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -2.7 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):4.404

Electronic energy of H2 binding, ΔE = 0.3 kcal/mol

Ethalpy of H2 binding, ΔH° = 1.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 11.7 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):4.735

Electronic energy of H2 binding, ΔE = -20.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -20.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -10.6 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):3.350

Electronic energy of H2 binding, ΔE = -14.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -15.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -4.3 kcal/mol

xyz coordinates: Download