Frustrated Lewis Pairs Database

FLPID: 0BN15034

FLP

LA-LB distance (d/Å):1.601

hydride affinity (ΔG°H/eV) :-4.14

proton affinity (ΔG°H+/eV) :8.17

HOMO-LUMO Gap (ΔEg/eV):7.5

hardness of LA (η/eV):0.139

softness of LA (S/eV):3.604

CM5 charge of LA (e):-0.157

CM5 charge of LB (e):-0.240

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):3.015

Electronic energy of H2 binding, ΔE = -9.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -3.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 4.9 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):2.758

Electronic energy of H2 binding, ΔE = -7.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -5.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 7.1 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):2.931

Electronic energy of H2 binding, ΔE = -26.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -23.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -10.6 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):2.910

Electronic energy of H2 binding, ΔE = -32.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -28.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -14.5 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):3.159

Electronic energy of H2 binding, ΔE = -36.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -34.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -20.3 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):2.996

Electronic energy of H2 binding, ΔE = -23.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -21.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -9.5 kcal/mol

xyz coordinates: Download