Frustrated Lewis Pairs Database

FLPID: 0BN15033

FLP

LA-LB distance (d/Å):1.602

hydride affinity (ΔG°H/eV) :-4.17

proton affinity (ΔG°H+/eV) :8.19

HOMO-LUMO Gap (ΔEg/eV):7.6

hardness of LA (η/eV):0.139

softness of LA (S/eV):3.585

CM5 charge of LA (e):-0.157

CM5 charge of LB (e):-0.238

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):2.969

Electronic energy of H2 binding, ΔE = -9.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -3.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 6.0 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):2.758

Electronic energy of H2 binding, ΔE = -8.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -6.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 6.2 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):2.882

Electronic energy of H2 binding, ΔE = -26.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -24.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -13.4kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):2.869

Electronic energy of H2 binding, ΔE = -32.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -28.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -13.6 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):3.164

Electronic energy of H2 binding, ΔE = -36.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -33.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -19.7 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):2.995

Electronic energy of H2 binding, ΔE = -23.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -21.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -9.1 kcal/mol

xyz coordinates: Download