Frustrated Lewis Pairs Database

FLPID: 0BN15032

FLP

LA-LB distance (d/Å):1.642

hydride affinity (ΔG°H/eV) :-4.44

proton affinity (ΔG°H+/eV) :8.83

HOMO-LUMO Gap (ΔEg/eV):7.0

hardness of LA (η/eV):0.129

softness of LA (S/eV): 3.863

CM5 charge of LA (e):-0.151

CM5 charge of LB (e):-0.216

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):3.085

Electronic energy of H2 binding, ΔE = -2.7 kcal/mol

Ethalpy of H2 binding, ΔH° = 3.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 11.1 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):2.781

Electronic energy of H2 binding, ΔE = -6.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -5.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 7.5 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):2.854

Electronic energy of H2 binding, ΔE = -23.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -21.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -9.7 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):2.831

Electronic energy of H2 binding, ΔE = -28.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -25.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -11.3 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):3.429

Electronic energy of H2 binding, ΔE = -26.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -24.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -11.5 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):2.966

Electronic energy of H2 binding, ΔE = -20.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -19.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -6.7 kcal/mol

xyz coordinates: Download