Frustrated Lewis Pairs Database

FLPID: 0BP16073

FLP

LA-LB distance (d/Å):1.989

hydride affinity (ΔG°H/eV) :-3.94

proton affinity (ΔG°H+/eV) :8.99

HOMO-LUMO Gap (ΔEg/eV):7.3

hardness of LA (η/eV):0.135

softness of LA (S/eV):3.707

CM5 charge of LA (e):-0.236

CM5 charge of LB (e):0.172

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):3.378

Electronic energy of H2 binding, ΔE = 22.0 kcal/mol

Ethalpy of H2 binding, ΔH° = 25.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 29.6 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.402

Electronic energy of H2 binding, ΔE = 18.6 kcal/mol

Ethalpy of H2 binding, ΔH° = 19.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 28.7 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 3.559

Electronic energy of H2 binding, ΔE = 0.6 kcal/mol

Ethalpy of H2 binding, ΔH° = 2.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 12.5 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):4.885

Electronic energy of H2 binding, ΔE = 8.0 kcal/mol

Ethalpy of H2 binding, ΔH° = 9.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 17.7 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):4.203

Electronic energy of H2 binding, ΔE = -5.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -4.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 7.4 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 3.866

Electronic energy of H2 binding, ΔE = 2.0 kcal/mol

Ethalpy of H2 binding, ΔH° = 3.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 12.8 kcal/mol

xyz coordinates: Download