Frustrated Lewis Pairs Database

FLPID: 0BP16072

FLP

LA-LB distance (d/Å):2.061

hydride affinity (ΔG°H/eV) :-4.45

proton affinity (ΔG°H+/eV) :8.10

HOMO-LUMO Gap (ΔEg/eV):8.1

hardness of LA (η/eV):0.150

softness of LA (S/eV):3.344

CM5 charge of LA (e):-0.216

CM5 charge of LB (e):0.165

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):3.612

Electronic energy of H2 binding, ΔE = 2.9 kcal/mol

Ethalpy of H2 binding, ΔH° = 6.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 10.8 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.819

Electronic energy of H2 binding, ΔE = 5.8 kcal/mol

Ethalpy of H2 binding, ΔH° = 6.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 14.4 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 3.949

Electronic energy of H2 binding, ΔE = -14.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -13.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -5.8 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):3.637

Electronic energy of H2 binding, ΔE = -28.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -26.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -15.2 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 4.286

Electronic energy of H2 binding, ΔE = -20.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -20.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -10.1 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 3.896

Electronic energy of H2 binding, ΔE = -9.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -9.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 0.7 kcal/mol

xyz coordinates: Download