Frustrated Lewis Pairs Database

FLPID: 0BP16071

FLP

LA-LB distance (d/Å):2.081

hydride affinity (ΔG°H/eV) :-4.19

proton affinity (ΔG°H+/eV) :8.16

HOMO-LUMO Gap (ΔEg/eV):7.5

hardness of LA (η/eV):0.138

softness of LA (S/eV):3.617

CM5 charge of LA (e):-0.216

CM5 charge of LB (e):0.160

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 3.518

Electronic energy of H2 binding, ΔE = 7.7 kcal/mol

Ethalpy of H2 binding, ΔH° = 11.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 14.9 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.811

Electronic energy of H2 binding, ΔE = 13.8 kcal/mol

Ethalpy of H2 binding, ΔH° = 14.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 21.9 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):3.646

Electronic energy of H2 binding, ΔE = -9.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -9.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -0.4 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):3.596

Electronic energy of H2 binding, ΔE = -20.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -18.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -8.7 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):3.921

Electronic energy of H2 binding, ΔE = -19.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -19.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -9.1 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):3.905

Electronic energy of H2 binding, ΔE = -7.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -7.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 1.9 kcal/mol

xyz coordinates: Download