Frustrated Lewis Pairs Database

FLPID: 0BN13012

FLP

LA-LB distance (d/Å):3.035

hydride affinity (ΔG°H/eV) :-3.38

proton affinity (ΔG°H+/eV) :7.71

HOMO-LUMO Gap (ΔEg/eV):5.8

hardness of LA (η/eV):0.107

softness of LA (S/eV):4.694

CM5 charge of LA (e):-0.097

CM5 charge of LB (e):-0.331

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 2.878

Electronic energy of H2 binding, ΔE = 2.1 kcal/mol

Ethalpy of H2 binding, ΔH° = 8.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 18.5 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.031

Electronic energy of H2 binding, ΔE = 1.7 kcal/mol

Ethalpy of H2 binding, ΔH° = 3.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 18.2 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):2.973

Electronic energy of H2 binding, ΔE = -15.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -14.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -0.7 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å): 3.030

Electronic energy of H2 binding, ΔE = -24.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -20.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -4.4 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 3.073

Electronic energy of H2 binding, ΔE = -19.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -16.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -1.3 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):3.027

Electronic energy of H2 binding, ΔE = -14.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -14.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 1.0 kcal/mol

xyz coordinates: Download