Frustrated Lewis Pairs Database

FLPID: 0BN13011

FLP

LA-LB distance (d/Å):3.056

hydride affinity (ΔG°H/eV) :-3.48

proton affinity (ΔG°H+/eV) :7.76

HOMO-LUMO Gap (ΔEg/eV):5.8

hardness of LA (η/eV):0.107

softness of LA (S/eV):4.690

CM5 charge of LA (e):-0.091

CM5 charge of LB (e):-0.330

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):2.861

Electronic energy of H2 binding, ΔE = 1.9 kcal/mol

Ethalpy of H2 binding, ΔH° = 8.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 17.7 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 3.077

Electronic energy of H2 binding, ΔE = -5.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -4.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 6.8 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):3.008

Electronic energy of H2 binding, ΔE = -11.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -10.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 2.9 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):3.048

Electronic energy of H2 binding, ΔE = -20.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -16.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -0.9 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):3.120

Electronic energy of H2 binding, ΔE = -16.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -13.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 2.9 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):3.069

Electronic energy of H2 binding, ΔE = -7.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -6.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 8.6 kcal/mol

xyz coordinates: Download