Frustrated Lewis Pairs Database

FLPID: 0BP15046

FLP

LA-LB distance (d/Å):3.238

hydride affinity (ΔG°H/eV) :-2.68

proton affinity (ΔG°H+/eV) :7.48

HOMO-LUMO Gap (ΔEg/eV):6.9

hardness of LA (η/eV):0.126

softness of LA (S/eV):3.963

CM5 charge of LA (e):0.041

CM5 charge of LB (e):-0.032

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):3.071

Electronic energy of H2 binding, ΔE = 21.7 kcal/mol

Ethalpy of H2 binding, ΔH° = 24.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 34.1 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.005

Electronic energy of H2 binding, ΔE = 1.1 kcal/mol

Ethalpy of H2 binding, ΔH° = 1.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 14.8 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):3.182

Electronic energy of H2 binding, ΔE = -3.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -2.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 10.0 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):3.254

Electronic energy of H2 binding, ΔE = -7.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -5.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 5.3 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):3.234

Electronic energy of H2 binding, ΔE = -16.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -15.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -4.1 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 3.283

Electronic energy of H2 binding, ΔE = -7.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -6.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 4.6 kcal/mol

xyz coordinates: Download