Frustrated Lewis Pairs Database

FLPID: 0BP15045

FLP

LA-LB distance (d/Å):3.267

hydride affinity (ΔG°H/eV) :-3.23

proton affinity (ΔG°H+/eV) :7.65

HOMO-LUMO Gap (ΔEg/eV):6.8

hardness of LA (η/eV):0.126

softness of LA (S/eV):3.973

CM5 charge of LA (e):0.067

CM5 charge of LB (e):-0.032

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):3.137

Electronic energy of H2 binding, ΔE = 17.8 kcal/mol

Ethalpy of H2 binding, ΔH° = 21.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 29.9 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 3.243

Electronic energy of H2 binding, ΔE = -6.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -5.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 2.7 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 3.268

Electronic energy of H2 binding, ΔE = -7.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -6.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 5.9 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å): 3.297

Electronic energy of H2 binding, ΔE = -7.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -5.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 5.1 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):3.288

Electronic energy of H2 binding, ΔE = -17.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -15.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -3.9 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 3.277

Electronic energy of H2 binding, ΔE = -11.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -10.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 2.8 kcal/mol

xyz coordinates: Download