Frustrated Lewis Pairs Database

FLPID: 0BP15044

FLP

LA-LB distance (d/Å):3.052

hydride affinity (ΔG°H/eV) :-2.79

proton affinity (ΔG°H+/eV) :7.57

HOMO-LUMO Gap (ΔEg/eV):7.6

hardness of LA (η/eV):0.139

softness of LA (S/eV):3.590

CM5 charge of LA (e):0.064

CM5 charge of LB (e):-0.026

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 3.100

Electronic energy of H2 binding, ΔE = 16.7 kcal/mol

Ethalpy of H2 binding, ΔH° = 19.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 30.9 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 3.098

Electronic energy of H2 binding, ΔE = -0.6 kcal/mol

Ethalpy of H2 binding, ΔH° = 0.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 13.6 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 3.291

Electronic energy of H2 binding, ΔE = -8.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -6.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 7.1 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):3.289

Electronic energy of H2 binding, ΔE = -7.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -5.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 6.0kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):3.206

Electronic energy of H2 binding, ΔE = -16.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -15.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -3.2 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):3.298

Electronic energy of H2 binding, ΔE = -10.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -8.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 6.4 kcal/mol

xyz coordinates: Download