Frustrated Lewis Pairs Database

FLPID: 0BP15042

FLP

LA-LB distance (d/Å):3.257

hydride affinity (ΔG°H/eV) :-2.71

proton affinity (ΔG°H+/eV) :7.62

HOMO-LUMO Gap (ΔEg/eV):6.7

hardness of LA (η/eV):0.124

softness of LA (S/eV):4.041

CM5 charge of LA (e):0.037

CM5 charge of LB (e):-0.004

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 3.160

Electronic energy of H2 binding, ΔE = 29.5 kcal/mol

Ethalpy of H2 binding, ΔH° = 32.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 41.3 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.260

Electronic energy of H2 binding, ΔE = -6.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -5.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 3.8 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 3.250

Electronic energy of H2 binding, ΔE = -9.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -7.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 1.3 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):3.252

Electronic energy of H2 binding, ΔE = -6.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -4.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 4.6 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):3.235

Electronic energy of H2 binding, ΔE = -15.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -14.2kcal/mol

Gibbs free energy of H2 binding, ΔG° = -3.9 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):3.227

Electronic energy of H2 binding, ΔE = -8.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -7.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 1.9 kcal/mol

xyz coordinates: Download