Frustrated Lewis Pairs Database

FLPID: 0BP15041

FLP

LA-LB distance (d/Å):3.262

hydride affinity (ΔG°H/eV) :-2.94

proton affinity (ΔG°H+/eV) :7.62

HOMO-LUMO Gap (ΔEg/eV):6.8

hardness of LA (η/eV):0.126

softness of LA (S/eV):3.976

CM5 charge of LA (e):0.058

CM5 charge of LB (e):-0.007

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):2.976

Electronic energy of H2 binding, ΔE = 21.5 kcal/mol

Ethalpy of H2 binding, ΔH° = 24.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 33.2 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 2.953

Electronic energy of H2 binding, ΔE = 3.9 kcal/mol

Ethalpy of H2 binding, ΔH° = 4.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 15.4 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):3.213

Electronic energy of H2 binding, ΔE = -8.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -7.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 0.6 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å): 3.276

Electronic energy of H2 binding, ΔE = -6.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -5.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 4.1 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 3.269

Electronic energy of H2 binding, ΔE = -14.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -13.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -4.7 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 3.188

Electronic energy of H2 binding, ΔE = -7.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -6.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 2.8 kcal/mol

xyz coordinates: Download