Frustrated Lewis Pairs Database

FLPID: 0BN17031

FLP

LA-LB distance (d/Å):4.637

hydride affinity (ΔG°H/eV) :-4.79

proton affinity (ΔG°H+/eV) :7.75

HOMO-LUMO Gap (ΔEg/eV):4.3

hardness of LA (η/eV):0.097

softness of LA (S/eV): 5.129

CM5 charge of LA (e):-0.056

CM5 charge of LB (e):-0.345

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):4.422

Electronic energy of H2 binding, ΔE = -9.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -2.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 6.7 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):4.645

Electronic energy of H2 binding, ΔE = -4.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -3.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 5.4 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):4.580

Electronic energy of H2 binding, ΔE = -17.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -15.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -2.1 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):4.923

Electronic energy of H2 binding, ΔE = -11.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -9.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 4.7 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):4.600

Electronic energy of H2 binding, ΔE = -16.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -13.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 0.5 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):4.898

Electronic energy of H2 binding, ΔE = -18.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -16.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -2.7 kcal/mol

xyz coordinates: Download