Frustrated Lewis Pairs Database

FLPID: 0BN17021

FLP

LA-LB distance (d/Å):1.719

hydride affinity (ΔG°H/eV) :-3.31

proton affinity (ΔG°H+/eV) :8.50

HOMO-LUMO Gap (ΔEg/eV):8.3

hardness of LA (η/eV):0.153

softness of LA (S/eV):3.264

CM5 charge of LA (e):-0.003

CM5 charge of LB (e):-0.241

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 2.783

Electronic energy of H2 binding, ΔE = 1.3 kcal/mol

Ethalpy of H2 binding, ΔH° = 6.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 13.6 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 2.888

Electronic energy of H2 binding, ΔE = -2.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -0.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 11.6 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):2.931

Electronic energy of H2 binding, ΔE = -16.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -15.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -4.7 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å): 2.992

Electronic energy of H2 binding, ΔE = -27.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -24.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -10.4 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 2.994

Electronic energy of H2 binding, ΔE = -31.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -29.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -16.6 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 2.941

Electronic energy of H2 binding, ΔE = -20.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -19.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -7.4kcal/mol

xyz coordinates: Download