Frustrated Lewis Pairs Database

FLPID: 0BN13031

FLP

LA-LB distance (d/Å):2.807

hydride affinity (ΔG°H/eV) :-4.74

proton affinity (ΔG°H+/eV) :7.96

HOMO-LUMO Gap (ΔEg/eV):6.2

hardness of LA (η/eV):0.114

softness of LA (S/eV):4.403

CM5 charge of LA (e):-0.057

CM5 charge of LB (e):-0.358

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):3.036

Electronic energy of H2 binding, ΔE = -20.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -13.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -4.5 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.041

Electronic energy of H2 binding, ΔE = -14.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -11.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 2.1 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):3.089

Electronic energy of H2 binding, ΔE = -39.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -36.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -23.4 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):3.068

Electronic energy of H2 binding, ΔE = -42.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -37.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -21.4 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 3.176

Electronic energy of H2 binding, ΔE = -44.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -41.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -28.0 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):3.095

Electronic energy of H2 binding, ΔE = -40.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -37.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -23.2 kcal/mol

xyz coordinates: Download