Frustrated Lewis Pairs Database

FLPID: 0BP17041

FLP

LA-LB distance (d/Å):3.183

hydride affinity (ΔG°H/eV) :-3.62

proton affinity (ΔG°H+/eV) :7.40

HOMO-LUMO Gap (ΔEg/eV):6.1

hardness of LA (η/eV):0.111

softness of LA (S/eV):4.491

CM5 charge of LA (e):-0.075

CM5 charge of LB (e):-0.018

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):3.179

Electronic energy of H2 binding, ΔE = 3.1 kcal/mol

Ethalpy of H2 binding, ΔH° = 7.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 17.1 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 3.120

Electronic energy of H2 binding, ΔE = -5.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -3.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 11.6 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):3.299

Electronic energy of H2 binding, ΔE = -5.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -3.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 10.8 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):3.122

Electronic energy of H2 binding, ΔE = -25.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -22.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -6.4 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 3.259

Electronic energy of H2 binding, ΔE = -13.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -12.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -0.3 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 3.237

Electronic energy of H2 binding, ΔE = -4.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -2.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 13.3 kcal/mol

xyz coordinates: Download