Frustrated Lewis Pairs Database

FLPID: 0BP18021

FLP

LA-LB distance (d/Å):3.882

hydride affinity (ΔG°H/eV) :-3.85

proton affinity (ΔG°H+/eV) :7.59

HOMO-LUMO Gap (ΔEg/eV):5.8

hardness of LA (η/eV):0.106

softness of LA (S/eV):4.714

CM5 charge of LA (e):-0.071

CM5 charge of LB (e):0.018

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 3.710

Electronic energy of H2 binding, ΔE = 10.1 kcal/mol

Ethalpy of H2 binding, ΔH° = 13.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 24.2 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.850

Electronic energy of H2 binding, ΔE = 8.2 kcal/mol

Ethalpy of H2 binding, ΔH° = 9.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 24.8 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 3.924

Electronic energy of H2 binding, ΔE = -10.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -8.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 5.8 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å): 4.363

Electronic energy of H2 binding, ΔE = -20.7 kcal/mol

Ethalpy of H2 binding, ΔH° = -18.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 0.1 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 4.332

Electronic energy of H2 binding, ΔE = -8.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -6.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 10.1 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 3.869

Electronic energy of H2 binding, ΔE = -8.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -6.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 9.8 kcal/mol

xyz coordinates: Download