Frustrated Lewis Pairs Database

FLPID: 0BP13051

FLP

LA-LB distance (d/Å):2.958

hydride affinity (ΔG°H/eV) :-3.62

proton affinity (ΔG°H+/eV) :41.56

HOMO-LUMO Gap (ΔEg/eV):5.9

hardness of LA (η/eV):0.108

softness of LA (S/eV):4.640

CM5 charge of LA (e):-0.091

CM5 charge of LB (e):0.039

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 3.142

Electronic energy of H2 binding, ΔE = 11.6 kcal/mol

Ethalpy of H2 binding, ΔH° = 15.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 23.2 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 3.382

Electronic energy of H2 binding, ΔE = 11.0 kcal/mol

Ethalpy of H2 binding, ΔH° = 12.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 26.4 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 3.512

Electronic energy of H2 binding, ΔE = 1.9 kcal/mol

Ethalpy of H2 binding, ΔH° = 4.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 17.1 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å):3.170

Electronic energy of H2 binding, ΔE = -14.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -12.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 2.8 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 3.902

Electronic energy of H2 binding, ΔE = 8.4 kcal/mol

Ethalpy of H2 binding, ΔH° = 9.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 23.2 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å):3.123

Electronic energy of H2 binding, ΔE = 4.8 kcal/mol

Ethalpy of H2 binding, ΔH° = 6.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 21.1 kcal/mol

xyz coordinates: Download