Frustrated Lewis Pairs Database

FLPID: 0BP13041

FLP

LA-LB distance (d/Å):2.176

hydride affinity (ΔG°H/eV) :-3.47

proton affinity (ΔG°H+/eV) :7.77

HOMO-LUMO Gap (ΔEg/eV):6.0

hardness of LA (η/eV):0.110

softness of LA (S/eV):4.560

CM5 charge of LA (e):-0.196

CM5 charge of LB (e):0.146

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 3.220

Electronic energy of H2 binding, ΔE = 20.2 kcal/mol

Ethalpy of H2 binding, ΔH° = 23.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 29.6 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 3.257

Electronic energy of H2 binding, ΔE = 13.4 kcal/mol

Ethalpy of H2 binding, ΔH° = 14.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 26.8 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 3.450

Electronic energy of H2 binding, ΔE = 7.6 kcal/mol

Ethalpy of H2 binding, ΔH° = 9.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 20.8 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å): 3.414

Electronic energy of H2 binding, ΔE = 16.5 kcal/mol

Ethalpy of H2 binding, ΔH° = 18.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 30.1 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):3.761

Electronic energy of H2 binding, ΔE = 16.1 kcal/mol

Ethalpy of H2 binding, ΔH° = 17.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 29.4 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 3.746

Electronic energy of H2 binding, ΔE = 15.5 kcal/mol

Ethalpy of H2 binding, ΔH° = 17.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 28.4 kcal/mol

xyz coordinates: Download