Frustrated Lewis Pairs Database

FLPID: 0BP13033

FLP

LA-LB distance (d/Å):2.014

hydride affinity (ΔG°H/eV) :-2.59

proton affinity (ΔG°H+/eV) :8.64

HOMO-LUMO Gap (ΔEg/eV):6.1

hardness of LA (η/eV):0.112

softness of LA (S/eV):4.474

CM5 charge of LA (e):-0.253

CM5 charge of LB (e):-0.054

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 2.919

Electronic energy of H2 binding, ΔE = 30.0 kcal/mol

Ethalpy of H2 binding, ΔH° = 33.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 40.9 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å):3.335

Electronic energy of H2 binding, ΔE = 26.2 kcal/mol

Ethalpy of H2 binding, ΔH° = 27.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 38.1 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 3.422

Electronic energy of H2 binding, ΔE = 17.5 kcal/mol

Ethalpy of H2 binding, ΔH° = 18.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 29.3 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å): 3.423

Electronic energy of H2 binding, ΔE = -3.8 kcal/mol

Ethalpy of H2 binding, ΔH° = -1.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 10.2 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å):2.014

Electronic energy of H2 binding, ΔE = 4.9 kcal/mol

Ethalpy of H2 binding, ΔH° = 5.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 15.9 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 3.450

Electronic energy of H2 binding, ΔE = 13.7 kcal/mol

Ethalpy of H2 binding, ΔH° = 14.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 25.9 kcal/mol

xyz coordinates: Download