Frustrated Lewis Pairs Database

FLPID: 0BP13032

FLP

LA-LB distance (d/Å):2.069

hydride affinity (ΔG°H/eV) :-2.72

proton affinity (ΔG°H+/eV) :8.15

HOMO-LUMO Gap (ΔEg/eV):6.4

hardness of LA (η/eV):0.117

softness of LA (S/eV):4.268

CM5 charge of LA (e):-0.228

CM5 charge of LB (e):0.149

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 3.007

Electronic energy of H2 binding, ΔE = 25.2 kcal/mol

Ethalpy of H2 binding, ΔH° = 29.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 37.2 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 3.316

Electronic energy of H2 binding, ΔE = 13.7 kcal/mol

Ethalpy of H2 binding, ΔH° = 14.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 27.0 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):3.462

Electronic energy of H2 binding, ΔE = 6.2 kcal/mol

Ethalpy of H2 binding, ΔH° = 7.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 18.6 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å): 2.078

Electronic energy of H2 binding, ΔE = -13.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -11.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 2.2 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 3.527

Electronic energy of H2 binding, ΔE = 7.1 kcal/mol

Ethalpy of H2 binding, ΔH° = 6.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 19.2 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 3.488

Electronic energy of H2 binding, ΔE = 10.4 kcal/mol

Ethalpy of H2 binding, ΔH° = 11.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 24.2 kcal/mol

xyz coordinates: Download