Frustrated Lewis Pairs Database

FLPID: 0BP13031

FLP

LA-LB distance (d/Å):2.198

hydride affinity (ΔG°H/eV) :-3.54

proton affinity (ΔG°H+/eV) :7.63

HOMO-LUMO Gap (ΔEg/eV):6.1

hardness of LA (η/eV):0.113

softness of LA (S/eV):4.436

CM5 charge of LA (e):-0.191

CM5 charge of LB (e):0.131

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 3.164

Electronic energy of H2 binding, ΔE = 11.3 kcal/mol

Ethalpy of H2 binding, ΔH° = 14.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 20.1 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 3.323

Electronic energy of H2 binding, ΔE = 12.1 kcal/mol

Ethalpy of H2 binding, ΔH° = 12.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 24.0 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):3.432

Electronic energy of H2 binding, ΔE = 6.2 kcal/mol

Ethalpy of H2 binding, ΔH° = 7.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 17.5 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å): 2.337

Electronic energy of H2 binding, ΔE = -14.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -12.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -0.2 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 3.717

Electronic energy of H2 binding, ΔE = 6.9 kcal/mol

Ethalpy of H2 binding, ΔH° = 6.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 18.1 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 3.489

Electronic energy of H2 binding, ΔE = 10.8 kcal/mol

Ethalpy of H2 binding, ΔH° = 11.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 22.7 kcal/mol

xyz coordinates: Download