Frustrated Lewis Pairs Database

FLPID: 0BP11012

FLP

LA-LB distance (d/Å):1.910

hydride affinity (ΔG°H/eV) :-4.10

proton affinity (ΔG°H+/eV) :9.02

HOMO-LUMO Gap (ΔEg/eV):5.4

hardness of LA (η/eV):0.099

softness of LA (S/eV):5.036

CM5 charge of LA (e):-0.093

CM5 charge of LB (e):-0.002

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 3.129

Electronic energy of H2 binding, ΔE = 1.8 kcal/mol

Ethalpy of H2 binding, ΔH° = 5.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 15.3 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 3.074

Electronic energy of H2 binding, ΔE = -8.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -7.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 4.1 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 3.497

Electronic energy of H2 binding, ΔE = -23.6 kcal/mol

Ethalpy of H2 binding, ΔH° = -21.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -8.1 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å): 3.317

Electronic energy of H2 binding, ΔE = -44.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -40.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -25.6 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 3.009

Electronic energy of H2 binding, ΔE = -26.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -26.4 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -14.2 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 3.240

Electronic energy of H2 binding, ΔE = -29.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -28.3 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -16.2 kcal/mol

xyz coordinates: Download