Frustrated Lewis Pairs Database

FLPID: 0BP11011

FLP

LA-LB distance (d/Å):1.910

hydride affinity (ΔG°H/eV) :-3.85

proton affinity (ΔG°H+/eV) :7.90

HOMO-LUMO Gap (ΔEg/eV):5.3

hardness of LA (η/eV):0.098

softness of LA (S/eV):5.106

CM5 charge of LA (e):-0.094

CM5 charge of LB (e):-0.004

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å):3.008

Electronic energy of H2 binding, ΔE = 0.3 kcal/mol

Ethalpy of H2 binding, ΔH° = 4.1 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 11.8 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 3.058

Electronic energy of H2 binding, ΔE = -9.4 kcal/mol

Ethalpy of H2 binding, ΔH° = -8.5 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 3.7 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å):3.493

Electronic energy of H2 binding, ΔE = -24.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -22.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -9.0 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å): 3.066

Electronic energy of H2 binding, ΔE = -45.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -41.7 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -28.3 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 3.003

Electronic energy of H2 binding, ΔE = -27.3 kcal/mol

Ethalpy of H2 binding, ΔH° = 26.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -15.1 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 3.609

Electronic energy of H2 binding, ΔE = -23.2 kcal/mol

Ethalpy of H2 binding, ΔH° = -22.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -9.4 kcal/mol

xyz coordinates: Download