Frustrated Lewis Pairs Database

FLPID: 0BP06011

FLP

LA-LB distance (d/Å): 6.247

hydride affinity (ΔG°H/eV):-5.30

proton affinity (ΔG°H+/eV):7.97

HOMO-LUMO Gap (ΔEg/eV): 4.5

hardness of LA (η/eV):0.083

softness of LA (S/eV):6.033

CM5 charge of LA (e): -0.062

CM5 charge of LB (e): 0.006

xyz coordinates: Download

FLP_H2

LA-LB distance (d/Å): 6.211

Electronic energy of H2 binding, ΔE = -5.3 kcal/mol

Ethalpy of H2 binding, ΔH° = -1.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 8.8 kcal/mol

xyz coordinates: Download

FLP_CO2

LA-LB distance (d/Å): 6.254

Electronic energy of H2 binding, ΔE = -4.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -4.0 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 4.9 kcal/mol

xyz coordinates: Download

FLP_H2O

LA-LB distance (d/Å): 6.318

Electronic energy of H2 binding, ΔE = -17.9 kcal/mol

Ethalpy of H2 binding, ΔH° = -15.6 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -3.6 kcal/mol

xyz coordinates: Download

FLP_H2CO

LA-LB distance (d/Å): 6.320

Electronic energy of H2 binding, ΔE = -14.0 kcal/mol

Ethalpy of H2 binding, ΔH° = -11.9 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 2.1 kcal/mol

xyz coordinates: Download

FLP_HCOOH

LA-LB distance (d/Å): 6.320

Electronic energy of H2 binding, ΔE = -12.5 kcal/mol

Ethalpy of H2 binding, ΔH° = -10.8 kcal/mol

Gibbs free energy of H2 binding, ΔG° = 4.1 kcal/mol

xyz coordinates: Download

FLP_CH3OH

LA-LB distance (d/Å): 6.333

Electronic energy of H2 binding, ΔE = -19.1 kcal/mol

Ethalpy of H2 binding, ΔH° = -17.2 kcal/mol

Gibbs free energy of H2 binding, ΔG° = -3.8 kcal/mol

xyz coordinates: Download